|
|
|
EYES |
Contact with eyes may cause severe irritation and possible eye burns. |
SKIN: |
May cause severe irritation and possible burns. |
INGESTION: |
May cause gastrointestinal irritation with nausea, vomiting, and diarrhea. |
INHALATION: |
May cause irritation and burns to the respiratory tract. |
CHROMIUM |
May cause histological fibrosis of the lungs. There are some references to chromium causing lung and/or nasal cancer. In addition, chromium metal has caused tumors in laboratory animals via implant and intravenous routes. Chromium is listed as a Confirmed Human Carcinogen by the ACGIH (American Conference of Governmental Industrial Hygienists). |
MANGANESE |
Dust inhalation may cause tightness and pain in chest, coughing, and difficulty in breathing. Inhilation of dust may cause headache, nausea, vomiting, shortness of breath, or blurred vision. Dust may irritate skin or eyes. Ingestion may cause central nervous system depression. Prolonged inhilation of Manganese in the form of its inorganic compounds may cause Manganism. Target organs: Respiratory system, central nervous system, blood, kidneys. Medical conditions generally aggravated by exposure: Chronic respiratory disease, liver or kidney disorders, psychiatric disorders, alcoholism, and nerve system disorders. |
MOLYBDENUM |
Chronic inhilation of molybdenum compounds by experimental animals has caused appetite and weight loss, diarrhea, muscular incoordination, hair loss and gout. Excessive intake of molybdenum may interfere with copper metabolism. |
TUNGSTEN |
If substantial quantities of dusts are swallowed, give person, if concsious, a large amount of water, induce vomiting and seek medical attention. |
|
PBT assesment
No data available
|
|
vPvB assessment
No data available
|
SECTION 3: Composition/information on ingredients
3.1. |
Substances |
|
This product is not a substance ‑ This is not applicable
|
3.2. |
Mixtures |
|
Ingredients:
METAL |
% |
SYMBOL |
CAS NO |
EC/EG NO |
ACGIH 8 HR TLV |
OSHA 8 HR PEL |
|
IRON |
<1 |
Fe |
7439-89-6 |
231-096-4 |
5 mg/m3 |
10mg/m3 |
COBALT |
61 |
Co |
7440-48-4 |
231-158-0 |
0,05mg/m3 |
No data |
SILICON |
<1 |
Si |
7440-21-3 |
231-130-8 |
10 mg/m3 |
10 mg/m3 (total dust)
5 mg/m3 (respiratory dust) |
MOLYBDENUM |
6 |
Mo |
7439-98-7 |
231-107-2 |
Not established |
Not established |
CHROMIUM |
25 |
Cr |
7440-47-3 |
231-157-5 |
0.5 mg/m3 |
0,5 mg/m3
CRVI compounds: Ceiling=0,1mg/m3 |
MANGANESE |
<1 |
Mn |
7439-96-5 |
231-105-1 |
5 mg/m3 |
5 mg/m3 |
TUNGSTEN |
5 |
W |
7440-33-7 |
231-143-9 |
5mg/m³ |
10 mg/m³ |
|
Note: % values are in weight percent and reflect nominal composition.
Note: 'x' denotes a content of less than one percent
SECTION 4: First aid measures
4.1. |
Description of first aid measures |
|
EYE CONTACT: |
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. |
SKIN CONTACT: |
Scrub skin thoroughly with soap and water. If victim is conscious and alert, give 2-4 cupfuls of milk or water |
INGESTION: |
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Induce vomiting. **Never give anything by mouth to an unconscious person. Get medical aid. |
INHALATION: |
Remove affected person to fresh air and assist with additional oxygen if necessary. Get first aid if other symptoms appear.
|
|
4.2. |
Most important symptoms and effects, both acute and delayed |
|
No data available
|
4.3. |
Indication of any immediate medical attention and special treatment needed |
|
No data available
|
SECTION 5: Fire-fighting measures
5.1. |
Extinguishing media |
|
Metal fire powders, sand
|
5.2. |
Special hazards arising from the substance or mixture |
|
Heating Beyond the melting range may generate fumes which are not flammable
|
5.3. |
Advice for fire-fighters |
|
Wear protective clothing and use a self-contained breathing apparatus
|
SECTION 6: Accidental release measures
6.1. |
Personal precautions, protective equipment and emergency procedures |
|
For non-emergency personnel
Use proper personal protective equipment as described in section 8.
For emergency responders
Use proper personal protective equipment as described in section 8.
|
6.2. |
Environmental precautions |
|
Collect contaminated materials in separate containers. Discharge according to local regulations.
|
6.3. |
Methods and material for containment and cleaning up |
|
Avoid creating dust and pick-up using mechanical means
|
6.4. |
Reference to other sections |
|
No data available
|
SECTION 7: Handling and storage
7.1. |
Precautions for safe handling |
|
Ensure the workspace has proper ventilation
Do not consume substances during work.
General protective and hygiene measures
Wash hands before and after breaks. Remove contaminated clothing immediately. Do not ingest, or allow to come into contact with the eyes.
|
7.2. |
Conditions for safe storage, including any incompatibilities |
|
Keep container closed in a ventilated area
|
7.3. |
Specific end use(s) |
|
No data available
|
SECTION 8: Exposure controls/personal protection
8.1. |
Control parameters |
|
Occupational exposure limit values
|
8.2. |
Exposure controls |
|
RESPIRATORY: |
RESPIRATORY: Provide general ventilation and local exhaust to keep levels below the TLV stated in SECTION 3. Wear a NIOSH approved respirator for dust exceeding the TLVs. |
| Latex gloves are recommended while grinding, heat resistant gloves should be worn while casting and handling hot metals or molds. |
EYE PROTECTION: |
Wear eye protection suitable to each individual operation. |
OTHER: |
Wear apron, lab coat or other protective clothing. |
|
SECTION 9: Physical and chemical properties
9.1. |
Information on basic physical and chemical properties |
|
Appearance: |
WHITE |
Odor: |
Not
Applicable |
pH: |
Not
Applicable |
Boiling
Point: |
Not
Applicable |
Melting
Range: |
1350-1385 °C |
Flash
Point: |
Not
Applicable |
Flammability: |
Not
Applicable |
Autoflammability: |
Not
Applicable |
Explosive
Properties: |
Not
Applicable |
Oxidizing
Properties: |
Not
Applicable |
Vapor
Pressure: |
Not
Applicable |
Solubility(Water/Fat): |
Insoluble |
|
9.2. |
Other information |
|
No data available
|
SECTION 10: Stability and reactivity
10.1. |
Reactivity |
|
At ordinary and high (below the melting range) temperatures, the material oxidizes but is stable. At very high temperatures the alloy produces fumes.
|
10.2. |
Chemical stability |
|
Product is stable under normal storage and handling conditions. See Section 7.
|
10.3. |
Possibility of hazardous reactions |
|
Hydrogen gas can possibly form if the product comes into contact with acid
|
10.4. |
Conditions to avoid |
|
N/A if the product is handled according to the Instructions for Use
|
10.5. |
Incompatible materials |
|
Acid
|
10.6. |
Hazardous decomposition products |
|
None are known
|
SECTION 11: Toxicological information
11.1. |
Information on toxicological effects |
|
No data is available other than the information provided in Sections 2 and 3
|
SECTION 12: Ecological information
12.1. |
Toxicity |
|
No data available
|
12.2. |
Persistence and degradability |
|
No data available
|
12.3. |
Bio-accumulative potential |
|
No data available
|
12.4. |
Mobility in soil |
|
No data available
|
12.5. |
Results of PBT and vPvB assessment |
|
No data available
|
12.6. |
Other adverse effects |
|
No data available
|
SECTION 13: Disposal considerations
13.1. |
Waste treatment methods |
|
Product:
Always recover all waste material and send to Department A at The Argen Corporation for refining.
Packaging:
Empty container completely and dispose according to local regulations.
|
SECTION 14: Transport information
14.1. |
Transport ADR/RID/AND |
|
This product is not subject to ADR/RID/AND regulations
|
14.2. |
Transport IMDG |
|
This product is not subject to IMDG regulations
|
14.3. |
Transport ICAO-TI / IATA |
|
This product is not subject to ICAO-Ti / IATA regulations
|
14.4. |
Other information |
|
No data available
|
|
No data available
|
14.5. |
Environmental hazards |
|
No data is available other than the information provided in Sections 2 and 3
|
|
This product is not subject to ICAO-Ti / IATA regulations
|
14.6. |
Special precautions for user |
|
none
|
14.7. |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code |
|
Not applicable
|
SECTION 15: Regulatory information
15.1. |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
|
Germany:
Wassergefährdungsklasse WGK (VwVwS): WGK-1 (self-assessed)
|
15.2. |
Chemical Safety Assessment |
|
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
|
SECTION 16: Other information
16.1. |
Training advice |
|
In addition to health, safety and environmental training programs for their workers, companies must ensure that workers read, understand and apply the requirements of this SDS.
|
16.2. |
Disclaimer |
|
The information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof. However, THE ARGEN CORPORATION makes no representations as to the completeness of accuracy thereof and information is supplied upon the condition that the persons receiving the above material will make there own determination as to its suitability for their purposes prior to use. In no event will "THE ARGEN CORPORATION" be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. No representations or warranties, either expressed or implied, or merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the product to which information refers.
|
|